OPTIMASI KONSENTRASI ASAM SULFAT DAN KECEPATAN PENGADUKAN PADA PROSES HIDROLISIS AMPAS TEBU MENJADI FURFURAL
DOI:
https://doi.org/10.34151/technoscientia.v5i2.537Keywords:
bagasse, furfural, hydrolysis, sulfuric acidAbstract
ABSTRACT
Hydrolysis of bagasse in the presence of sulfuric acid catalyst to produce furfural was studied. This objective of this work was to study the effects of catalyst consentration and stirrer speed on yield of furfural. The experiment were conducted by reacting bagas-se with sulfuric acid in a three neck flask sized 500 mL equipped with stirrer, heater, condenser, and thermometer. The reaction condition studied were catalyst concentration ranging from 4% to 20% and stirrer speed from 100 rpm to 500 rpm at reaction temperature 100ºC and reaction time 120 minutes. The concentration of furfural was analyzed to calculate the yield of furfural. The analysis of bagasse obtained that the water content of 6.76% and pentosan content of 18.86%. The results show that yield of furfural reached a maximum at the catalyst concentration of 8% is 5.79% and the yield of furfural reached an optimum at the stirrer speed of 400 rpm is 6.29%.
References
Badan Penelitian dan Pengembangan Pertanian, 2007, Prospek dan Arah Pengembangan Agribisnis Tebu, Edisi 2, Departemen Pertanian, Jakarta.
Dunlop, A. P., 1948, Furfural Formation and Behavior, Ind. Eng. Chem., Vol. 40, pp. 204 – 209, The Quaker Oats Company, Chicago.
Gandana, S. G., 1982. Pengawasan Giling Cara Hawaii pada Kondisi di Indonesia, Majalah Perusahaan Gula Th. XIV No. 2 Juni 1982, BP3G Pasuruan.
Griffin, R. C., 1927, Technical Methods of Analysis, 2nd ed., pp. 491 – 494, McGraw–Hill Book Company, New York.
Groggins, P. H., 1958, Unit Processes in Organic Synthesis, 5th ed., pp. 775 – 777, McGraw-Hill Book Company, New York.
Hidajati, N., 2006, Pengolahan Tongkol Jagung sebagai Bahan Pembuatan Furfural, Jurnal Ilmu Da-sar Vol. 8, p. 48, Jurusan Kimia FMIPA, Universitas Negeri Surabaya.
Hughes, E. E. and Acree, S. F., 1937, Analysis of Mixtures of Furfural and Methylfurfural, pp. 318–321, National Bureau of Standards, Washington.
Husin, 2007, Analisis Serat Bagas, (http://www.free.vlsm.org/, diakses tanggal 6 Juli 2009).
Kirk, R. E. and Othmer, D., 1955, Encyclopedia of Chemical Technology, Vol. 10, pp. 237–250, The Interscience Encyclopedia Inc., New York.
Miksusanti, 2004, Pengaruh Penyimpanan terhadap Struktur Kimia Karbohidrat pada Ampas Tebu, Makalah Falsafah Sains, Program Pasca Sarjana - S3, Institut Pertanian Bogor.
Penebar Swadaya, 1992, Pembudidayaan Tebu di Lahan Sawah dan Tegalan, Penerbit Penebar Swadaya, Jakarta.
Mui, N.T., 1996, Effect of Management Practices on Yield and Quality of Sugar Cane and on Soil Fertility, Goat and Rabbit Research Centre, Son Tay, Ha Tay, Vietnam.
Sastrowijoyo, 1998, Klasifikasi Tebu, (http://arluki.wordpress.com/2008/10/14/ /tebu sugarcane/, diakses tanggal 8 Desember 2009).
Sudarmadji, S., Haryono, B., dan Suhardi, 1997, Prosedur Analisis untuk Bahan Makanan dan Pertanian, Edisi 4, Fakultas Teknologi Pertanian, Universitas Gadjah Mada, Yogyakarta.
Suharto, 2006, Pemanfaatan Limbah Tandan Kosong Sawit untuk Produksi Commercial Grade Furfural, Laporan Akhir Kumulatif Program Penelitian dan Pengembangan IPTEK, LIPI.
Suharto dan Susanto, H., 2006, Pengaruh Konsentrasi Katalis terhadap Perolehan Furfural pada Hidrolisis Tongkol Jagung, Seminar Nasional IPTEK Solusi Kemandirian Bangsa, Yogyakarta.
Susanto, H., Suharto, dan Kismurtono, 2004, Rekayasa Digester Pemasakan Tandan Kosong Sawit untuk Produksi Furfural dan Pulp, Laporan Akhir RUT IX.
Witono, J. A., 2005, Produksi Furfural dan Turunannya: Alternatif Peningkatan Nilai Tambah Ampas Tebu Indonesia, (http://www. chem-is-try.org/, diakses tanggal 21 Desember 2009).