SINTESIS FURFURAL DARI KULIT BUAH KAPUK RANDU DENGAN KATALISATOR ASAM KHLORIDA
DOI:
https://doi.org/10.34151/technoscientia.v9i1.147Keywords:
kapok shell, furfural, hydrolysis, hydrochloric acidAbstract
Hydrolysis of kapok shell in the presence of hydrochloric acid catalyst to produce furfural was studied. This objective of this work was to study the effects of catalyst concentration and reaction time on yield of furfural. The experiment were conducted by reacting kapok shell with hydrochloric acid in a three neck flask sized 500 mL equipped with stirrer, heater, condenser, and thermometer. The reaction condition studied were catalyst concentration ranging from 0,025 N to 0,2 N and reaction time from 30 minutes to 180 minutes. The concentration of furfural was analyzed to calculate the yield of furfural. The initial analysis of kapok shell obtained that the water content of 6.75%, ash content of 2.31%, and pentosan content of 22.72%. The results show that yield of furfural reached a maximum at the catalyst concentration is 8.01% and the yield of furfural reached an optimum at the reaction time for 180 minutes is 8.03%.
References
Arnold, D. R. and Buzzard, J. L., 2003, A Novel and Patented Process for Furfural Production, Proceeding of The South African Chemical Engi-neering Congress.
Brazdausks, P., Puke, M., Vedernikovs, N., and Kruma, I., 2013, Influence of Biomass Pretreatment Process Time on Furfural Extraction from Birch Wood, Environmental and Climate Technologies, vol. 11, pp. 1 – 11.
Hidajati, N., 2006, Pengolahan Tongkol Jagung sebagai Bahan Pembuatan Furfural, Jurnal Ilmu Dasar Vol. 8, p. 48, Jurusan Kimia FMIPA, Universitas Negeri Surabaya.
Kazemi, M. and Zand-Monfared, M. R., 2010, Furfural Production from Pisthachio Green Hulls as Agricultural Residues, Journal of Applied Chemical Researches, Vol. 3, No. 12, pp.19-24.
Kirk, R. E. and Othmer, D., 2004, Furan Derivatives: on Encyclopedia of Chemical Technology, Vol. 10, pp. 237 – 250, The Interscience Encyclopedia Inc., New York.
Mitarlis, Ismono, dan Tukiran, 2011, Pengembangan Metode Sintesis Furfural Berbahan Dasar Campuran Limbah Pertanian dalam Rangka Mewujudkan Prinsip Green Chemistry, Jurnal Manusia dan Lingkungan, Vol. 18, No. 3, pp. 191 – 199.
Sudarmadji, S., Haryono, B., dan Suhardi, 1997, Prosedur Analisis untuk Bahan Makanan dan Pertanian, Edisi 4, Fakultas Teknologi Pertanian, Universitas Gadjah Mada, Yogyakarta.
Suharto, 2006, Pemanfaatan Limbah Tandan Kosong Sawit untuk Produksi Commercial Grade Furfural, Laporan Akhir Kumulatif – Program Penelitian dan Pengembangan IPTEK, LIPI.
Suharto dan Susanto, H., 2006, Pengaruh Konsentrasi Katalis terhadap Perolehan Furfural pada Hidrolisis Tongkol Jagung, Seminar Nasional IPTEK Solusi Kemandirian Bangsa, Yogyakarta.
Witono, J. A., 2005, Produksi Furfural dan Turunannya: Alternatif Peningkatan Nilai Tambah Ampas Tebu Indonesia, (http://www.chem-is-try.org/, diakses tanggal 2 Juli 2016).
Wittcoff, H. A., Reuben, B. G., and Plotkin, J. S., 2004, Industrial Organic Chemicals, 2nd ed., John Wiley & Sons, Inc., Danvers.
Zeitsch, K.J., 2000, The Chemistry and Technology of Furfural and Its Many By-Products, Elsevier Science B.V., Amstredam
Website:
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